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Carbon Monoxide

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Mattlt

09-01-2004 08:02:15




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The other night, we had a rescue call for a guy that decided to have too many beers, and start his Harley in a small shop. You guessed it, he was laid out due to carbon monoxide. Seems he's going to be fine.

This got me thinking. At what point would an engine die from sucking in CO and other exhaust products? I realize a newer vehicle with all it's oxygen sensors, etc would probably compensate for the oxygen deficient atmosphere. But what about an old motorcyle, tractor, or small engine?

I'm not really too keen on experimenting with this one. Thought I'd run it by the experts.

Thanks.

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JLW

09-01-2004 17:32:23




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 Re: Carbon Monoxide in reply to Mattlt, 09-01-2004 08:02:15  
The brain has several safety systems that protects it. When the oxygen amount needed to maintain responsiveness is reached, the brain shuts down to protect itself. If the shut down is long enough the brain begins to die due to oxygen starvation. Carbon Monoxide bonds to the redblood cells and prohibits those cells from obtaining oxygen and that is the cause of oxygen deprivation. There is still enough oxygen in the air to allow ignition inside an engine, but that oxygen is not allowed to get to the brain because the CO bonding to the redblood cells.

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buickanddeere

09-02-2004 05:57:14




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 Re: Carbon Monoxide in reply to JLW, 09-01-2004 17:32:23  
The human body still operates at oxygen levels too low to support combustion of most fuels.

Concentration of CO in air Inhalation time and toxic developed 50 parts per million (ppm) Safety level as specified by the Health and Safety Executive 200 PPM Slight headache within 2-3 hours 400 PPM Frontal headache within 1-2 hours, becoming widespread in 3 hours 800 PPM , that's only .08% Dizziness, nausea, convulsions within 45 minutes, insensible in 2 hours

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Mattlt

09-02-2004 08:35:36




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 Re: Carbon Monoxide in reply to buickanddeere, 09-02-2004 05:57:14  
Any idea at what point (ppm of CO) an engine would start sputtering? That's what I'd be curious to find out.

Put another way, What is "oxygen deficient" for an engine? If it's less than 16% for a human, what's deficient for an engine?

Thanks guys, for all the great answers. I've gleaned a lot of useful information off these boards over the last few years. They are really valuable!



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buickanddeere

09-02-2004 19:48:14




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 Re: Carbon Monoxide in reply to Mattlt, 09-02-2004 08:35:36  
Well on the old diesel electric submarines. They used to figure it was time to surface for fresh air when a flame can"r be started or kept going on a lighter. There is a non halon fire supression gas mixture for much modified halon systems. A high volume of C02, nitrogen(N2) and something else if memory serves correctly. The sheer volume of this gas mixture loweres the O2 level below the point for flames but has enough O2 for people to stagger out of the area to safety.

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Mark - IN.

09-01-2004 17:11:14




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 Re: Carbon Monoxide in reply to Mattlt, 09-01-2004 08:02:15  
I have a '79 FL that I stroked up to 103", and then back down to 96" because I got tired of the 103"er breakin everytime I took out. I'd just kicked it over and had it puttin out in the closed garage that I was going to open in a second or two, and for the life of me don't know how I heard the phone ring over the drags, but I did. Instead of shuttin down, I ran into the house to say "Hello, I'll call you back", but it didn't work out that way. A few minutes later, I heard it puttin slower and slower and ran out to shut it down so the air-cooled stroker wouldn't seize. The exhaust gagged the crap out of me. It was gaggin the S&S carb too, and it was gonna choke out soon, but had anyone been in there, no doubt they'd have been long dead before it was. Doesn't take a lot of carbon monoxide to kill a person, and certainly not as much as I walked out into.

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Irv

09-01-2004 17:10:15




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 Re: Carbon Monoxide in reply to Mattlt, 09-01-2004 08:02:15  
Ron is right. I have read of a couple people who tried suicide with new cars. They failed! The new engines burn so clean that you would have trouble giving yourself a headache. Irv



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TimFL

09-01-2004 11:37:40




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 Re: Carbon Monoxide in reply to Mattlt, 09-01-2004 08:02:15  
Interesting question. I think we have determined that exhaust is converted to H2O and CO2 neither of which are harmful. But a car and a human body require O, oxygen. Putting a car in a sealed garage and running it would seemingly combine the fuel with the oxygen convert it to H2O and CO2 until there was no longer enough O for the car or the human to function.



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Paul in Mich

09-01-2004 14:11:26




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 Re: Carbon Monoxide in reply to TimFL, 09-01-2004 11:37:40  
I"m puttin my money on the car to be running long after the man has met his maker.



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Ford Man

09-01-2004 12:42:24




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 Re: Carbon Monoxide in reply to TimFL, 09-01-2004 11:37:40  
Tim,
Speaking from personal experience ,you are dead on !
Even though CO2 is harmless , you must have enough oxygen to live.

About 20 years ago, my old boss left a propane forklift running in our shop all day long.He was trying to charge the batteries ! Anyway, I figured he was smart enough to open a door or something but he was not. I remember feeling woozy and sweating a lot as the level of CO2 grew , then I remember waking up in a chair in the parking lot and another employee shaking me and asking if I was OK .

I was lucky and wound up with only a bad headache.

I suppose the forklift would have eventually stopped on its own due to lack of oxygen but I don't think I will be a part of that experiment!

Ford Man

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T_Bone

09-01-2004 13:23:04




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 Re: Carbon Monoxide in reply to Ford Man, 09-01-2004 12:42:24  
Hi Tim,

That would mean a gasser is 100% efficent burn! That is not possible with a carbon base fuel.

Take for example a combustion burner using a carbon vapor gas fuel supply. Even with the most efficent combustion process we still have CO as a by-product of combustion with a 98% burn ratio and thats with using a after burner process.

In a gasoline engine were using a liquid carbon based fuel that has more CO as a by-product of combustion as were having to change the liquid fuel into a saturated vapor fuel and that process is not 100%.

T_Bone

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Gerald J.

09-01-2004 19:56:49




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 Re: Carbon Monoxide in reply to T_Bone, 09-01-2004 13:23:04  
Once the engine gets the oxygen portion in the room air reduced, its likely to create more CO than it would normally because it hasn't the oxygen available to complete the reaction to CO2.

I've had a dose of CO once and I don't want another!!!!

Gerald J.



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Mattlt

09-01-2004 08:51:19




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 Re: Carbon Monoxide in reply to Mattlt, 09-01-2004 08:02:15  
P.S. I don't mean to imply that the engine would/should shut off before the CO concentration reached harmful levels. I think we all agree that even a low concentration of CO over a period of time is harmful.

Pretty safe to assume that a "victim" would be long gone well before the engine would shut off.



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T_Bone

09-01-2004 08:40:55




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 Re: Carbon Monoxide in reply to Mattlt, 09-01-2004 08:02:15  
Hi Matt,

On a 24ft x 24ft x 8ft sealed shop, it would take approx 9.2min for a typical gasser car engine to start using recirculated air intake.

With puter controled engines then the ECM will see a fuel enrichment and start in the defueling mode of the ECM program.

Without running a bunch more numbers, I would guess about 1hr for a typical 8cyl auto gasser engine at idle to fill a room with deadly CO.

With a single cylider engine, I would think about 4hrs as they don"t have a ECM program to start defueling the engine and the CO would increase at a faster rate.

T_Bone

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Allan in NE

09-01-2004 08:58:06




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 Re: Carbon Monoxide in reply to T_Bone, 09-01-2004 08:40:55  
T Bone,

On computer controlled outfits, they always start in open loop anyway. They don't drop into closed loop until the coolant reaches 151 degrees F.

Allan



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Loren

09-01-2004 21:16:02




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 Yep and on the old feedback carbs.. in reply to Allan in NE, 09-01-2004 08:58:06  
they take long enough to get to closed loop sometimes that is this senario they may never make it. The quality of intake may go downhill faster than the warmup/feedback system gets to closedloop.



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TheRealRon

09-01-2004 08:18:54




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 Re: Carbon Monoxide in reply to Mattlt, 09-01-2004 08:02:15  
I'm no expert on this but I know two things for sure...

1) Modern vehicles with O2 sensors have cat-cons and they don't make enough CO to hurt anybody.

2) In the days before cat-cons, a couple of love-struck teenage neighbors locked themselves in the garage with the engine running. They were dead long before the car ran out of gas which took about 8 hours. Had the garage been air-tight the engine may have died earlier due to lack of oxygen, hard to say. Interesting question.

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Red Dave

09-01-2004 10:47:00




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 Re: Carbon Monoxide in reply to TheRealRon, 09-01-2004 08:18:54  
"Modern vehicles with O2 sensors have cat-cons and they don't make enough CO to hurt anybody."

Don't bet your life on that, because you will lose.



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TheRealRon

09-01-2004 11:00:19




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 Re: Carbon Monoxide in reply to Red Dave, 09-01-2004 10:47:00  
The Fed emission standard for CO is near zero. Assuming the catcon has not been fouled, breathing the exhaust is safe.



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Red Dave

09-01-2004 11:09:46




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 Re: Carbon Monoxide in reply to TheRealRon, 09-01-2004 11:00:19  
If you are foolish enough to try it, be my guest.

But, I'm betting against you. RIP, My condolences to the family.

***Disclaimer***
To all others out there: Don't try this at home!



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harley1983

09-01-2004 11:29:35




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 Re: Carbon Monoxide in reply to Red Dave, 09-01-2004 11:09:46  
Ron"s family won"t know it cause they"re all in the house, remember?



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Paul in Mich

09-01-2004 13:56:49




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 Re: Carbon Monoxide in reply to harley1983, 09-01-2004 11:29:35  
Harley, With explicit instructions not to go outside when they hear the tractor running. Poor Ron, a victim of the unintended consequences of his own rules.



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True but ...

09-01-2004 11:39:34




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 Re: Carbon Monoxide in reply to harley1983, 09-01-2004 11:29:35  
... They are safe from that dangerous tractor of his. Phew !!!



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TheRealRon

09-01-2004 11:35:35




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 Re: Carbon Monoxide in reply to harley1983, 09-01-2004 11:29:35  
Apparently you sucked one too many bike exhaust pipe... enjoy that, do you?



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Harley1983

09-01-2004 12:06:18




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 Re: Carbon Monoxide in reply to TheRealRon, 09-01-2004 11:35:35  
Not really Ron, but what I really do enjoy is following your threads, because I don"t think T.V. writers could come up with some of the stuff you spew forth here and I have an endless supply of material that way. Keep er up and git er done, Harley



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Paul in Mich

09-01-2004 14:08:22




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 Re: Carbon Monoxide in reply to Harley1983, 09-01-2004 12:06:18  
Harley, I like you enjoy, and am amused at Ron"s cockamamie statements. I scan the threads daily looking for them so I can get my laugh for the day. I hope he continues his natural comedy act as no human being could ever write a script with such gut busting humor. Besides as long as we have Ron to champion the wrong side of any issue, it solidifys the correctness and validity of the other side. Ron, if you"re listening, keep it up, we love ya.

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Rockin' farmer

09-01-2004 09:23:33




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 Re: Carbon Monoxide in reply to TheRealRon, 09-01-2004 08:18:54  
Ron,

"1) Modern vehicles with O2 sensors have cat-cons and they don"t make enough CO to hurt anybody."

I thought the cat-cons were to convert Nitrogen Oxides from the exhaust gasses to CO among others. Another lesser of 2 evils thing. Perhaps I"ve been misled?

Rockin" Farmer



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Joe MN

09-01-2004 16:42:11




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 Re: Carbon Monoxide in reply to Rockin' farmer, 09-01-2004 09:23:33  
Link



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TheRealRon

09-01-2004 10:03:59




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 Re: Carbon Monoxide in reply to Rockin' farmer, 09-01-2004 09:23:33  
Single stage catcons remove CO and HC. They basically convert them to H2O and CO2, both of which are harmless.

Three-way catcons also remove NOx as well, converting them to N.

All catcons in current use are now three-way.



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John S-B

09-01-2004 21:29:30




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 Re: Carbon Monoxide in reply to TheRealRon, 09-01-2004 10:03:59  
H2O and CO2 are harmless huh? It does'nt take much of either in your lungs to be harmful. Any time the O2 concentration in the air drops below 16% you are in big trouble,it makes no difference what is displacing the O2.



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txblu

09-01-2004 11:19:01




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 Re: Carbon Monoxide in reply to TheRealRon, 09-01-2004 10:03:59  
Well I's pretty close. Gimme an E for effort.



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txblu

09-01-2004 09:55:26




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 Re: Carbon Monoxide in reply to Rockin' farmer, 09-01-2004 09:23:33  
CO2 + water. Carbon dioxide not harmful, not carbon monoxide, deadly. And yes it was to get rid of Nitrous Oxide in the atmosphere which makes smog among other things.

Mark



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Paul in Mich

09-01-2004 13:59:50




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 Re: Carbon Monoxide in reply to txblu, 09-01-2004 09:55:26  
Dang, txblu, All for the want of a teensy weensy molecule of oxygen.



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Harley1983

09-01-2004 20:20:19




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 Re: Carbon Monoxide in reply to Paul in Mich, 09-01-2004 13:59:50  
Okay. This should end it. CO2-1/3NO2+243xNOS1+x over y to the seventh power=brain fart till NC2=OT2C+4487 or 4487-OT2C=NC2 which is a non-combustable byproduct of duck$#it. Harley



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txblu

09-02-2004 06:18:43




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 Re: Carbon Monoxide in reply to Harley1983, 09-01-2004 20:20:19  
LOL I love this site with it's diversity..... Chemical PhD's and all....brain fart....more LOL.

Mark



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Paul in Mich

09-02-2004 05:14:05




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 Re: Carbon Monoxide in reply to Harley1983, 09-01-2004 20:20:19  
Not so fast Harley, your theory can only be proven providing the Mass of the gas of the A** remains at constant velocity thereby equalizing pressure on the brain. Duck Sh*t acts as a catylist only when ingested nasally at room temperature.



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harley1983

09-02-2004 08:22:55




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 Re: Carbon Monoxide in reply to Paul in Mich, 09-02-2004 05:14:05  
Ya, but anyvon who has duck in house to get to room temperature iss not tinking of zee mass pressure of zee @$$ gas, they are tinking of Someting to eat, Ya??



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txblu

09-02-2004 06:19:17




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 Re: Carbon Monoxide in reply to Paul in Mich, 09-02-2004 05:14:05  
You guys are too much!



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harley1983

09-02-2004 08:25:51




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 Re: Carbon Monoxide in reply to txblu, 09-02-2004 06:19:17  
By the way txblu, good luck on your retirement. Hope you have more time than I do. Since I quit working full time in town, I can"t find enough time to get anything down out here on the farm. Gonna have to go back to work just to get anything done. Happy 38th, Harley



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