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Thought I may as well put in my .02 worth too. I know you said you weren't sure of alloy composition. Most gold used for jewelry or dental applications is alloyed with copper or silver. It's possible that it may contain additional elements such as nickel, platinum, paladium or even zinc. Your silver may also be an alloy. It is quite commonly alloyed with copper which has the effect of lowering the melting point of the silver and reducing thermal and electrical conductivity. That would be an asset in this instance as the gold and silver would then be more closely matched in regard to metal properties that directly affect the joining process. By themselves, that is in their purest state, gold is described as having "good" electrical and thermal conductivity while silver is described as having excellent properties in that regard. Their melting points are fairly close with gold being 1950�F and silver being 1765�F. Gold has very good resistance to oxidation which is in your favor. That may be compromised slightly by some of the alloying constituents but overall is not of great concern. The shielding gas will easily take care of that. The greatest source of contamination will be your tungsten electrode. Silver is a different animal all together. If the silver is pure you will find that it will require a great deal more heat input than the gold. This is due to the fact that silver has that high rate of thermal conductivity. It is difficult to control the molten puddle as well because it is so fluid. Molten silver will readily absorb oxygen too. Unless you provide adequate shielding during the solidification process, you will experience a good deal of spatter and porosity as the oxygen that was absorbed in the molten state is being rejected during solidification. You can use either argon or helium as a gas shield. Choose the one which best fits the application. If you have a ag/cu alloy the argon should be good. Polarity of DCEN is normally used unless the metals you are joining are easily oxidized. With DCEN polarity the weld pool is narrower and the penetration is deeper than when using AC or DCEP. DCEN provides a narrower HAZ and that means less distortion and faster welding speeds. Sorry about the lengthy response. Turned out to be more like a dollar and a half rather than two cents.
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