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Hi Mark, There's many different types of gas valves, varible volume, constant volume, multi-stage and single stage and just as many control designs. These type of vlaves can be found on residentual heating units and probably a few more as the burner units get more efficient. For this example I'll use a simple single stage gas valve with thermocouple. A typical thermocouple generates 350mv when heated to design tempature. This voltage then is appiled to a coil on the main gas valve holding the valve open so a volume of gas can flow to the burners. If the thermocouple has too much heat beyond it's design limit, then it will not cool down fast enough to quit generating electricity thus holding open the main gas valve too long dumping excessive raw gas into the combustion chamber. For the sake of this discussion, lets say the mfg designed the combuston chamber for when the thermocouple at correct design tempature would allow .125cf of gas into the combustion chamber upon pilot flame failure. Now lets heat the thermocouple to twice the mfg design flame impringement length. In the real world it will take approx 3times as long for the thermocouple to cool down and shut off the main gas valve and now .5cf of raw gas is now dumped into the combustion chamber upom pilot flame failure or 4 times the mfg limit for the combustion chamber design. There are tests that have to be completed on a typical thermocouple system to insure the thermocouple is installed correct. To many variables in both parts and controls to cover here and is why there's books written on the subject that can't be covered on the internet. 4 times the gas volume beyond mfg design is alot of BOOM! T_Bone
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