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Isocyanates in paint

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Steve8N275777

05-29-2003 13:59:04




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I'm getting ready to do some painting on the 8N and am concerned with isocyanate exposure from hardeners. The benefits of using hardeners seem to make them the way to go, but the expense for a supplied air respirator for a one time usage seems hard to justify.

What have some of you done to lessen the risks in terms of:

-Paint alternatives (are there different hardeners or good paint systems that don't contain iso's?)

-Methods (outdoor spraying, brushing, etc.)

-Protection (build your own?)

-Bite the bullet and buy a supplied air system? (Is there a resale or rental market for this stuff?)

Just want to stay healthy and financially solvent.

Thanks for sharing any tips or experiences you've had.

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Mark G.

05-30-2003 10:32:38




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
I used to have a job where we sprayed industrial roof coatings and beside the health risks anything with Isocyanates in it broke down miserably when exposed to any UV rays for any length of time; in fact so badly that I can't see any benefits in using them. Any paint or coating that I have seen with Isoncyante in it turn faded, yellowed, or chalked badly in a short amount of time when out in the sun light. Who ever thought using a product that had no UV durably would be a good ingredient for an exterior paint or coating must have been smoking something or got to much Isocynate in his system in the lab. I'm not a chemist but I do no that the stuff is worthless outdoors.

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Willy-N

05-29-2003 20:20:52




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
When we painted the Power Wagon I used hardners in the primer and paint. Thought I would be OK by the window where the fresh air was coming in at. Wrong! I was also doing the mixing too. The fan was in the window blowing air at me and by the time we were done I was feeling like SH** and noticed the fan blades had red paint on them and so did my mustach! I was 20 ft from where we sprayed and the plume was going up to the ceiling down into the fan and right at me again. The painters had carbon masks and I had the cheap dust mask since I was not spraying paint. I sufferd for weeks afterwords and still cough up crap more than I used to (I smoke). My vision and breathing was affected and so was my thinking. No way am I getting close to that kind of paint again with out the best protection. I may have been lucky this time but not realy sure?? Time will tell. Been a while now but think it still affects me. Don't chance it for a 50.00 mask to protect yourself! Mark H.

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Airframer

05-29-2003 20:11:58




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
Hey Steve,

As the others have said iso's are bad. If you can have a well ventilated area, a regular full face cartridge mask will work well. Using an HVLP - High Volume Low Pressure gun will also do well. The main thing is to stay protected, the isocyanates are there. When you paint, sand or even during clean up of any over spray on the floor. Air supplied would be the best way, if you had access to an up to date paint shop. Otherwise a twin cartridge full face mask is the next alternative.
Just keep youself from breathing the crud. As was said; if you can smell it, taste it. The mask is not fitted correctly (Sealing), and the cartridges must be rated. Have shot gallons of Polyurethane paint on aircraft, and am doing well.
The main thing is to be safe, also keep others away during mixing, spraying and clean up.

Sincerely,
A-7D / F-16 Painter/Airframe Repairer

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Steve8N275777

05-29-2003 19:38:31




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
Thanks all - There sure is a wide diversity of opinion on this topic. I've got lots to think about.



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Jay 2NSC

05-29-2003 18:26:53




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
Hi Steve,please becareful,isocyanate is nothing to be playing with.This is the same chemical that make's super glue super.I was told by a chemist a few year's back that once this stuff get's in your lung's it set's up house and is there until you leave this earth.I have sprayed a many a vehicle with just a standard (charcoal) respirator.I hope I haven't done any long term damage?Take care,Jay 2NSC

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Adam P

05-29-2003 17:52:07




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
Hey Steve, Not to disagree with Dell on this, (Dell, If I never got the chance to thank you for so many wonderful posts, let me do so now!!! Thanks Dell!!!, you've helped us all out alot!!!.AP) OK Whether it be sprayed or brushed, or rolled, the hardener is a dangerous factor. It also is the main ingrediant to a wonderful enamel paint job. I might use a brush, with paint and hardener and some thinner, just to avoid the brush marks, and do a few coats on the underside and abused areas of the tractor. For safety, I would try to find a nice day to paint outside, and try to stay upwind of the paint. Also, the use of an HVLP paint rig will prevent overspray. (big clouds of mist) HVLP is a very neat way to go. 3M makes some decent resporators in the under 40 dollar range that you can use, However, they do not filter the isocyanates contained in the hardener. There is a great deal of talk on this in the paint and bodywork forum here at YTMAG. I have found that the HVLP market is getting pretty competitive, You should be able to find an acceptable gravity feed HVLP gun for under a 100 bucks.
Hope this helps,
Adam P

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MikeC

05-29-2003 18:11:47




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 Re: Re: Isocyanates in paint in reply to Adam P, 05-29-2003 17:52:07  
I just bought a real nice DeVilbiss HVLP on Ebay for $120. They had several in the $30-50 range but I was concerned about the quality. DeVilbiss seems to be pretty good. Like you said the prices are becoming much more competitive.



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MarkG

05-29-2003 17:28:54




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
Steve8N,

I have extensive experience with auto paints (as both a mixer and painter).
The hazards from isocyanates are very real, in fact, a former co-worker spent 3 days in the hospital because of isocyanate poisoning. If you follow tha basic rules of painting, you will have no problems and also minimize your risk of isocyanate poisoning.
1. Use a quality respirator-NOT a particle mask.
(If you can smell or "taste" the paint, your filters need to be changed or you don't have the right mask for the job.
2. Wear rubber gloves and avoid skin contact with the chemicals.
3. Ensure adequate ventilation. Outdoor spraying is fine if you can live with all of the dirt "goobers" which are flying around and seem to be unusually attracted to your fresh paint.
4. Heat helps. A heated booth (or warm outdoor temperatures/low humidity allow the paint to begin drying faster and minimize the attack of the "goobers."
5. Definitely use hardeners-they produce a more durable and chip-resistant finish. Old-fashioned synthetic enamel (such as NAPA/Martin-Senour "Synthol") will heat cure without using a hardening agent, but are not as desirable as more modern paints.
You don't need a supplied air or positive-pressure system to safely guard against iso's, so save your money.
Hope this info helps.
Good Luck.
MarkG

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Andy

05-29-2003 19:21:14




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 Re: Re: Isocyanates in paint in reply to MarkG, 05-29-2003 17:28:54  
Mark, I guess I have what would be considered a particle mask. (two filter pack type) How does a respirator differ? and do you know of any online sources?



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MikeC

05-29-2003 20:02:36




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 Re: Re: Re: Isocyanates in paint in reply to Andy, 05-29-2003 19:21:14  
There are a lot of places that carry quality respirators including Home Depot, Menards, Lowes, etc. I would consider buying one locally so the replacement filters are easier to find. I bought one on line a couple of years ago and never could find filters for it. Look for one rated for spray painting-there are some filters that are only for dust environments. A good one should cost around $40-50.

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Dell (WA)

05-29-2003 16:40:19




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 Re: Isocyanates in paint in reply to Steve8N275777, 05-29-2003 13:59:04  
Steve..... ....its the breathing of aerosol mist that pressure spray painting generates thats the major problem. When I getta roundtueitt, I'm gonna do a 20/20 paint job with brush on the castiron stuff and roller on the sheetmetal stuff. The hardners will flow the paint smooth and since you're NOT THINNING the paint for spraying, you'll get better coverage (thicker) and longer lasting paint.

Its good to do research on this stuff, but I don't think the non-aerosol vapors are as hazardous nor are you in a continious exposure situation, painting every day. Check your MSD sheets..... ...Dell

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Way wrong answer!

05-29-2003 18:05:09




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 Re: Re: Isocyanates in paint in reply to Dell (WA), 05-29-2003 16:40:19  
There are significant documented cases of Iscocyanates causing significant health issues with minimal exposure. Problems include:

Irritation
Sensitization and asthma
Hypersensitivity Pheumonitis
Cancer

As an example I'll quote from the CDC's website about 1 case of isocyanate exposure:

Two police officers developed asthma-like illness after a single exposure to TDI in the immediate vicinity of a tank car that had overturned on the highway [Luo et al. 1990]. After briefly directing traffic at the accident scene, both officers received medical care for severe symptoms, including burning eyes, throat irritation, cough, chest tightness, and difficult breathing. Treatment included steroids and a bronchodilator.

Both police officers developed a chronic bronchospastic disorder after their relatively brief exposure to high concentrations of TDI. Though considerable improvement has occurred in both cases, symptoms have persisted for more than 7 years. The estimated amount of inhaled isocyanate was the equvilant of painting an automobile with no breathing apparatus.

This is nothing to fool with.

Rodney

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ah yes . . . Dell (WA)

05-29-2003 18:34:18




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 Re: Re: Re: Isocyanates in paint in reply to Way wrong answer!, 05-29-2003 18:05:09  
Rodney..... ...ah yes, the comparison of exposure from a 50,000 gal tank spill vs the 1 gal of paint required to paint your tractor. Good comparison, good science. As I said, consult your MSD sheets. It's NOT benign, but I fault your logic..... ...respectfully, Dell



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Richard(WY)

05-29-2003 20:57:13




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 Re: Re: Re: Re: Isocyanates in paint in reply to ah yes . . . Dell (WA), 05-29-2003 18:34:18  
I am employed as a technician/chemist. I am HAZMAT, HAZWOPER, NUCLEAR RADIATION ETC. certified. Isocyanates are deadly. Exposure is accumulative in the body. They do things like interfere with blood gas efficiency in the oxygen/carbon dioxide exchange in the corpuscles, nerve damage and fine tissue damage also occur. Lung tissue and nerve tissue do not regenerate. Each and every exposure adds up to more permanent damage. Paints are volatile and easily converted into a fine aerosol mist that can be absorbed through the mucus membranes around the eyes, nose and mouth. The thinners also allow the paint to enter the skin unless barriers are used. When I paint I wear a special paint respirator, vinyl gloves and a protective jacket that is almost vapor proof. I also use vaseline on my exposed skin. Overkill? Maybe, but I plan on watching my grand daughter's wedding some day. All you armchair mechanics should plan on doing the same. For safety's sake err on the safe side. Buy the mask and use it. Keep it in good shape. Learn how to do proper fit tests on it. Stay around to read this board for another few years. One more thing while I am on my soapbox, if you don't know what the heck you are talking about.....shut up. Let what happened to Willy N be a lesson to all of us.

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Admit you are wrong for o

05-29-2003 19:56:04




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 Re: Re: Re: Re: Isocyanates in paint in reply to ah yes . . . Dell (WA), 05-29-2003 18:34:18  
What part of **The estimated amount of inhaled isocyanate was the equivilant of painting an automobile with no breathing apparatus** did you not understand?

It does not take 50K gallons to cause a problem. One ill informed mistake is all it takes to cause problems for a lifetime.

Pop used to paint an occasional car and would only wear particle masks. Maybe one every three-four years. Until he died he had lung problems for years. Never smoked either.

Lookie lookie at MarkGs post above. I betcha he is a much more informed authority on this since he is active in the field. Do a searchie searchie on Isocyanate. This stuff is nothing to fool with and to tell someone that the non-aerosol vapors are not hazardous is wrong and you need to admit it bucko. Understand???

Respectfully,
Rodney

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check your MSD sheet . .

05-29-2003 21:24:39




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 Re: Re: Re: Re: Re: Isocyanates in paint in reply to Admit you are wrong for o, 05-29-2003 19:56:04  
Rodney..... ...what part of "check your MSD sheet" didn't you understand?

I absolutely agree that isocyanates are NOT benign. Read 'em again, I didn't say it was NON-HAZARDOUS.

I said "Its good to do research on this stuff, but I don't think the non-aerosol vapors are as hazardous nor are you in a continuous exposure situation, painting every day. Check your MSD sheets..... ...Dell

ah yes, the comparison of exposure from a 50,000 gal tank spill vs the 1 gal of paint required to paint your tractor. Good comparison, good science. As I said, consult your MSD sheets. It's NOT benign, but I fault your logic..... ... respectfully, Dell"

And you said "This stuff is nothing to fool with and to tell someone that the non-aerosol vapors are not hazardous is wrong and you need to admit it bucko. Understand???"

Read 'em again, I didn't say NON-HAZARDOUS.
Its called personal responsiblility, check your MSD sheets..... .....respectfully, Dell

Who appearently didn't make it understandable enough for Rodney to understand DO NOT SNIFF THAT STUFF, it'll fry yer brains, and for that I apologize

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