The power company uses a chemical that kills all, any time of year and makes it look like a lunar landscape for 3-4 years. I've seen it used here in NY and in Michigan. I wouldn't let them use it on my property. What it is, I don't know.
Roundup pretty much relies on being sucked in by the plant and delivered to the roots BY that plant. That's why it works better in the Fall then in the Spring. Fall is the time when plants are gathering nutrients from above ground, to send down to the roots. Springtime is somewhat the opposite.
Years back, many used Atrazine for quick "contact kill", but I assume it's not legal for general use anymore.
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