What I would suggest is that you make sure that the well is not in any way susceptable to surface water contamination. That's a good practice whether you're spraying or not. As others have mentioned, Glyphosate is a very safe product as herbicides go. The LD50 is something like 4100 mg/Kg, so you'd die of a busted gut before you drank enough concentrated product to kill you.
Regardless, there will be a recomendation of an appropriate setback from water supplies on the label. Follow that, use common sense, and protect the well from surface water and you won't have a problem. I spose testing is not a bad idea either if you're worried about it, but you're probably more apt to find other things in the water other than Round-Up...
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Today's Featured Article - Gatherin of the Orange - by Rick Nikolich. In July of 1998 I was talking to fellow Allis Chalmers collector Mike Schilling about the annual "Gathering of The Orange" AC show coming up in August of 1999. He got this wild idea that we should get a convoy of AC tractors and drive them from Charlotte, Michigan 105 miles to LaGrange, Indiana.
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