Spraying yard

24D is a contact spray so the leaves must be present for absorption of the chemical to kill them. I would wait until there is more leaf surface before spraying.
 
I guess it depends on your location, we have had three weeks above freezing and days as high as low 80s so I sprayed mine last week. Middle Tennessee , have a lot of green weed called doc , is mostly what I killed.
 
There are two things to consider. 2,4 D works better in warm weather and in the fall when weeds are taking herbicide (and other things) down into their roots.
 

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