I'd start by reading the label. 2,4-D on emerged corn is a tricky business. You can mess with the growing point and make the stalk extremely brittle. Your better bet would be to buy some Rounduo ready corn. Generic Roundup can be bought fairly cheap and doesn't need any licensing to buy. Ideally you'd put down something pre emerge like Harness Extra, or Dual and come back if needed with a post treatment for any escape broadleaf plants. If you have a local Coop or agronomy store where you'd buy seed, fertilizer, etc. They will have a good plan for weed control in your area and tell you what licensing you need to have to buy and apply.
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