There are probably some good ones out there but I've never used them. I don't trust them. When I restore a car I get it all gone. On old machinery I think it is something you constantly have to battle. People really swear by some of those products though.
 
I have used OSPHO, a phosphorus solution which reacts with the rust to form a paintable surface. I try to remove all the rust that I can then clean with a commercial detergent and water, let dry well before painting.
 

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